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A local HNC/HNC approximation for the 2:2-RPM electrolytes at a charged wall
, P. Nielaba, T. Alts, F. Forstmann
Published in
1986
Volume: 85
   
Issue: 6
Pages: 3476 - 3481
Abstract
A local HNC/HNC approximation is proposed and applied to 2:2 electrolytes near a charged hard wall. The results are compared with Monte Carlo data and other theories such as HNC/HNC, HNC/MSA, BGY, and MPB5. A remarkable improvement of the density profiles and of the diffuse layer potential is obtained. We show that the HNC closure for the ion-ion correlations, when used in the local scheme, always gives better results than those obtained from the MSA closure. The necessary algorithm for solving the local HNC/HNC equations is also presented. © 1986 American Institute of Physics.
About the journal
JournalThe Journal of Chemical Physics
ISSN00219606