The developed method was employed In the synthesis or medicinally Important compounds and Intermediates in the organic synthesis. Herein we report a variety of novel iV-chloro derivatives of benzlsoxa/ole, benximldaiolcs and several other .V-chloro derivatives usinjj 1.2 equivalents or calcium hypochlorite. The process does not require any additives like acids or bases and produced moderate to excellent yields of desired products under mild conditions. © 2015 Scientific Publishers. All Rights Reserved.