In this work, simulation has been carried out for multipass Gas tungsten Arc Welding of SS316L and their effects were studied for thermal and residual stresses and compared with experimental results. The sequentially coupled thermo-mechanical, transient thermal and static structural analysis was modelled using ANSYS with relevant Ansys Parametric Design Language coding. Infrared thermography camera was used to obtain the real time temperatures during the welding. The effect of temperatures and the induced residual stresses of the weldment is measured with X-Ray diffraction technique. Tensile residual stresses have been identified at fusion zone and compressive stresses at heat affected zone. Pass wise temperature measurements were taken from analysis and experiment the agreement with 7.24%. The agreement of measured and analysed residual stress had an agreement with 16.66%.