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Carboxamide versus sulfonamide in peptide backbone folding: A case study with a hetero foldamer
, S.S. Kale, A.S. Kotmale, R.L. Gawade, V.G. Puranik, P.R. Rajamohanan, G.J. Sanjayan
Published in
PMID: 23473041
Volume: 15
Issue: 7
Pages: 1504 - 1507
Strikingly dissimilar hydrogen-bonding patterns have been observed for two sets of closely similar hetero foldamers containing carboxamide and sulfonamides at regular intervals. Although both foldamers maintain conformational ordering, the hydrogen-bonding pattern and backbone helical handedness differ diametrically. © 2013 American Chemical Society.
About the journal
JournalOrganic Letters