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Catalytic regeneration of a Th-H bond from a Th-O bond through a mild and chemoselective carbonyl hydroboration
, K. Makarov, N. Fridman, M.S. Eisen
Published in Royal Society of Chemistry
PMID: 30215091
Volume: 54
Issue: 78
Pages: 11001 - 11004
Here we present an unprecedented chemoselective hydroboration for aldehydes and ketones catalysed by actinides. The reaction features a very low catalyst loading (0.1-0.004 mol%) and quantitative product formation in less than 15 minutes, at room temperature. Thermodynamic and kinetic studies including stoichiometric and labeling studies with deuterated pinacolborane allow us to propose a plausible mechanism for this remarkable catalytic regeneration of a Th-H bond via carbonyl hydroboration. © 2018 The Royal Society of Chemistry.
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JournalData powered by TypesetChemical Communications
PublisherData powered by TypesetRoyal Society of Chemistry