In this study, cobalt ferrite and bismuth substituted cobalt ferrite (CoFe2−xBixO4 x=0, 0.1) nanoparticles were synthesized by two different methods viz combustion and co-precipitation. The nanoparticles were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), diffuse reflectance spectroscopy (DRS), scanning electron microscopy-energy dispersive X-ray analyzer (SEM-EDX) and vibrating sample magnetometer (VSM). The results of powder XRD pattern showed an increase in lattice parameter and decrease in particle size of cobalt ferrite by the substitution of bismuth. Catalytic activity of cobalt ferrite and bismuth substituted cobalt ferrite nanoparticles synthesized by two different methods were compared for the reduction of 4-nitrophenol to 4-aminophenol using NaBH4 as a reducing agent. © 2016 Elsevier B.V.

Sumathi S

Department of Chemistry

School of Advanced Sciences

Vellore Campus

Kiran V.S

Vellore Institute of Technology (VIT) is a private university located in&nbsp;Tamil Nadu, India. Founded in 1984, as Vellore Engineering College, the institution offers 20 undergraduate, 34 postgraduate, four integrated and four research programs. It has campuses in Vellore, Amravati, Bhopal and Chennai.

VIT is one of the top ranked private universities in India according to NIRF, THE and QS Rankings.&nbsp;Govt. of India has recognized&nbsp;VIT, Vellore as an&nbsp;Institution of Eminence. This has allowed VIT to take independent quality initiatives and move up in world ranking.

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VIT University

Journal of Magnetism and Magnetic Materials

In this study, yttrium doped zinc ferrite (ZnFe2−xYxO4x = 0.01–0.1) and yttrium and copper co-doped zinc ferrite (CuyZn1−yFe2−xYxO4x = 0.1 and y = 0.5) were synthesized by solution combustion method. The synthesized nanoparticles were authenticated by various techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy–energy dispersive X-ray analysis (SEM-EDAX) and UV–visible spectroscopy. The photocatalytic activity of synthesized nanoparticles was studied by performing the degradation of methylene blue (MB) under visible light. 95% of MB was degraded in 180 min using yttrium-doped zinc ferrite. 89% of MB was degraded in 30 min using copper and yttrium co-doped zinc ferrite under visible light using 10 mg of the catalyst and 50 µl of hydrogen peroxide. Photocatalytic degradation of colorless pollutant bisphenol A also carried out using the doped zinc ferrite. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

Journal of Materials Science: Materials in Electronics

Synthesis, characterization, optical and photocatalytic activity of yttrium and copper co-doped zinc ferrite under visible light

Chinese Journal of Chemical Engineering

Copper doped nickel aluminate: Synthesis, characterisation, optical and colour properties

A rapid synthetic technique is investigated for magnetic nanoparticles (Co1−yCuyFe2−xCexO4 (x = 0, y = 0), (x = 0.05, y = 0), (x = 0, y = 0.5), and (x = 0.05, y = 0.5)). The structure, morphology, optical and magnetic performance of prepared nanoparticles are analyzed by powder XRD, XPS, FT-IR, SEM-EDAX, TEM, DRS, and VSM. The photocatalytic activity of the synthesized nanoparticles for the removal of the Congo red (CR) dye and bisphenol A (BPA) from aqueous solution is examined by UV–visible spectrometer. Research indicates that the co-doping of Cu2+ and Ce3+ showed marked effect on the structural, optical, magnetic, and photocatalytic properties of the CoFe2O4 nanoparticles. DRS showed that the Co0.5Cu0.5Fe1.95Ce0.05O4 nanoparticles have lower band gap energy (0.78 eV) than other synthesized compounds. High removal percentage of CR and BPA (99.09% and 99.33%) was observed within 30 min and 180 min under visible and UV–light illumination respectively using Co0.5Cu0.5Fe1.95Ce0.05O4. The corresponding photocatalytic degradation kinetics and mechanism are analyzed. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.

Environmental Science and Pollution Research

Copper and cerium co-doped cobalt ferrite nanoparticles: structural, morphological, optical, magnetic, and photocatalytic properties

Herein we reported the photocatalytic and antibacterial activity of CoFe2O4, CoFe1.9Bi0.1O4 and Cu0.5Co0.5Fe1.9Bi0.1O4 nanoparticles obtained by solution combustion technique using glycine as a fuel. The obtained nanoparticles were analyzed by various techniques such as powder XRD, FTIR, UV-DRS and SEM-EDAX. The band gap value of CoFe2O4 nanoparticle is decreases gradually from 1.46 to 1.00 eV (CoFe1.9Bi0.1O4) and 0.85 eV (Cu0.5Co0.5Fe1.9Bi0.1O4) due to the doping of copper and bismuth. The photocatalytic activity of synthesized nanoparticles was evaluated for the degradation of congo red dye. 89 and 87% removal efficiency of congo red dye was achieved in 90 min under different light (UV and visible light) illumination utilizing 10 mg of Cu0.5Co0.5Fe1.9Bi0.1O4 catalyst. Antibacterial activity of the compounds was tested against two organisms Staphylococcus aureus and Escherichia coli by well diffusion method. Co-doping of copper and bismuth improved the antibacterial activity against the organisms S. aureus (29 mm) and E. coli (34 mm) when compared to cobalt ferrite. © 2018, Springer Science+Business Media, LLC, part of Springer Nature.

Photocatalytic and antibacterial activity of bismuth and copper co-doped cobalt ferrite nanoparticles

In this study, the authors synthesised gold nanoparticles (Au NPs) by a green approach using an aqueous extract of empty cotton boll peels (ECBPs) which was rapid, simple and inexpensive eco-friendly method compared to chemical and physical methods. The ECBP aqueous extract played a vital role in the reduction of Au+3 ions into Au NPs which was further confirmed by analytical characterisation. The phase purity and crystallinity of Au NPs were confirmed by X-ray diffraction analysis. The characteristic functional groups of synthesised Au NPs were identified by Fourier transform infrared analysis. The surface morphology and topography of Au NPs were studied by scanning electron microscopy and transmission electron microscopy analysis. Size with dispersion stability of Au NPs was determined by dynamic light scattering and zeta potential studies. In this study, the authors performed a catalytic activity of Au NPs using different pollutant organic dyes such as methylene blue and methyl orange. It also showed good antioxidant activity compared to standard ascorbic acid by using the standard 1,1-diphenyl-2-picryl-hydrazil method. Hence, this study concluded that ECBP mediated Au NPs could act as a promising material for degradation of dyes and antioxidant activity. © The Institution of Engineering and Technology 2017.

IET Nanobiotechnology

Synthesis of gold nanoparticles by cotton peels aqueous extract and their catalytic efficiency for the degradation of dyes and antioxidant activity

Zinc doped cobalt ferrite spinel nanoparticles were prepared by the microwave combustion method. All the samples were characterized by using X-ray diffraction technique (XRD), Scanning Electron Microscopy, energy dispersive X-ray analysis, UV-visible diffuse reflectance spectroscopy, Fourier transformed infrared (FT-IR) spectroscopy and vibrating sample magnetometry. The XRD patterns confirmed the formation of single phase CoFe2O4 inverse spinel structure without impurities. The lattice parameter increased from 8.380 to 8.396 Å with increasing Zn2+ fraction. The average crystallite sizes obtained by a Scherrer method varied between 46.22 nm and 30.79 nm. The estimated band gap energy values increases with an increasing zinc fraction (1.88-2.10 eV). The elemental composition of Zn, Co, and Fe was qualitatively obtained from energy dispersive X-ray (EDX) analysis. © 2015 Elsevier Ltd.

Materials Science in Semiconductor Processing

Microwave combustion synthesis of zinc substituted nanocrystalline spinel cobalt ferrite: Structural and magnetic studies

Background: p-Nitrophenol (PNP) occurs as contaminants of industrial effluents and it is the most important environmental pollutant and causes significant health and environmental risks, because it is toxic to many living organisms. Nevertheless, the information regarding PNP degradation pathways and their enzymes remain limited. Objective: To evaluate the efficacy of the Pseudomonas Putida 1274 for removal of PNP. Methods: P. putida MTCC 1274 was obtained from MTCC Chandigarh, India and cultured in the minimal medium in the presence of PNP. PNP degradation efficiency was compared under different pH and temperature ranges. The degraded product was isolated and analyzed with different chromatographic and spectroscopic techniques. Results: P. putida 1274 shows good growth and PNP degradation at 37°C in neutral pH. Acidic and alkali pH retarded the growth of P. putida as well as the PNP degradation. On the basis of specialized techniques, hydroquinone was identified as major degraded product. The pathway was identified for the biodegradation of PNP. It involved initial removal of the nitrate group and formation of hydroquinone as one of the intermediates. Conclusion: Our results suggested that P. putida 1274 strain would be a suitable aspirant for bioremediation of nitro-aromatic compounds contaminated sites in the environment. © 2014 Samuel et al.; licensee BioMed Central Ltd.

Fulltext

Journal of Environmental Health Science and Engineering

Bioremediation of p-Nitrophenol by Pseudomonas putida 1274 strain

The role of pH on the particle size and magnetic consequence of cobalt ferrite

Chinese Journal of Catalysis

Selective oxidation of sulfurs and oxidation desulfurization of model oil by 12-tungstophosphoric acid on cobalt-ferrite nanoparticles as magnetically recoverable catalyst

Journal	Data powered by TypesetJournal of Magnetism and Magnetic Materials
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ISSN	0304-8853
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