Every organization can develop their human competencies and capabilities based on collective effort of their human capital management from which high amount performance can be achieved. Human capital management put their practices to impart certain competencies based on organizational requirement. It is a collective and incorporated approach that employees are the assets of the organization and whose present value can be measure and whose future value can be build through investment in human capital. The research study has taken to examine the association between human capital indicator i.e. Knowledge accessibility and organizational performance from the perspective of executives employed in Pharmaceutical sector in Hyderabad. The result indicated that most of the executives find knowledge accessibility is a major significant factor in organization Human Capital. Also the study found an optimistic connection between two variables i.e. knowledge accessibility and organizational performance from the aspect of executives employed in Pharmaceutical companies in Hyderabad. The study provided limitations and direction for future research.