Semantic Associations are complex relationships between entities over metadata represented in a RDF graph. While searching for complex relationships, it is possible to find too many relationships between entities. Therefore, it is important to locate interesting and meaningful relations and rank them before presenting to the end user. In recent years e-learning systems have become very popular in all fields of higher education. In an e-learning environment, user may expect to search the semantic relationship paths between two concepts or entities. There may be numerous relationships between two entities which involve more intermediate entities. In order to filter the size of results set based on user's relevance, user may introduce one or more known intermediate entities. In this paper, we present a Modified bidirectional Breadth-First-Search algorithm for finding paths between two entities which pass through other intermediate entities and the paths are ranked according to the users' needs. We have evaluated our system through empirical evaluation. We have compared the execution time to discover the paths between entities for our proposed search method and existing method. According to our experiments our proposed algorithm improves search efficiently. The average correlation coefficient between the proposed system ranking and the human ranking is 0.69. It explains that our proposed system ranking is highly correlated with human ranking. © 2012, V and Krishnamurthi; licensee Springer.