Organostannoxane-based multiredox assemblies containing ferrocenyl peripheries have been readily synthesized by a simple one-pot synthesis, with quantitative yields. The reaction of triorganotin oxides, (nBuSn)2O with 2-cyano-3-ferrocenyl acrylic acid leads to the formation of [(nBu3SnOC(O)CNCHFc)n] polymeric structure. FT-IR, NMR, UV-Vis and emission spectroscopic techniques were performed for the characterization of [(nBu3SnOC(O)CNCHFc)n](Fc = η5C5H4-Fe-η5C5H4) polymeric structure. Electrochemical studies on these hybrid organotin/ferrocene systems reveal that most of them exhibit a single quasi-reversible oxidation peak. © 2017, Chemical Publishing Co. All rights reserved.

Palanisami N

Department of Chemistry

School of Advanced Sciences

Vellore Campus

David E

Fulltext

Vellore Institute of Technology (VIT) is a private university located in&nbsp;Tamil Nadu, India. Founded in 1984, as Vellore Engineering College, the institution offers 20 undergraduate, 34 postgraduate, four integrated and four research programs. It has campuses in Vellore, Amravati, Bhopal and Chennai.

VIT is one of the top ranked private universities in India according to NIRF, THE and QS Rankings.&nbsp;Govt. of India has recognized&nbsp;VIT, Vellore as an&nbsp;Institution of Eminence. This has allowed VIT to take independent quality initiatives and move up in world ranking.

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VIT University

Asian Journal of Chemistry

A mixed Cd(II) complex {[Cd(FcCOO)2(dpyam)(H2O)][Cd(dpyam)2 (H2O)2]·(ClO4)2·CH3OH} (1) (where FcCOO&nbsp;=&nbsp;ferrocenecarboxylic acid and dpyam&nbsp;=&nbsp;2,2′-dipyridylamine), has been synthesized and characterized by FT-IR, 1H &amp; 13C NMR, UV–Vis spectroscopy and elemental analysis. The molecular structure of compound 1 has been determined by the single crystal X-ray diffraction technique, which consists of mixed two different cadmium(II) complexes and two uncoordinated perchlorate ions. The crystal packing shows that the compound 1 self-assembled by intermolecular hydrogen bonding via pyridyl N–H⋯O and coordinated water O⋯H–O–H⋯O, to afford the molecule 2D supramolecular network. Compound 1 exhibits high-energy intraligand (π–π∗) fluorescence emission. In electrochemical studies of compound 1 shows negative potential compared with ferrocenecarboxylic acid due to formation of coordination complex with Cd ions. The antibacterial study against the distinct bacterial strains show compound 1 has significant activity.

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy

Monomeric mixed cadmium-2,2′-dipyridylamine complex derived from ferrocenecarboxylic acid: Structural, electrochemical and biological studies

Tetrahedron Letters

Synthesis and electronic properties of ferrocene-containing organic dyads

The reaction of MnCl2·4H2O with t-BuPO 3H2 in the presence of triethylamine afforded the tridecanuclear cage, [MnIIMnIII12(μ 4-O)6(μ-OH)6(O3P-t-Bu) 10(OH2)2(DMF)4] ·[2MeOH·4DMF] (1). The structural analysis of 1 reveals that it is a mixed-valent complex containing a [MnIIMnIII 12(μ4-O)6] core. The centre of the core is occupied by a MnII ion which is surrounded by 12 MnIII ions. The latter are connected to each other by six μ-OH- and 10 t-BuPO32- ligands. The vacant coordination sites of six MnIII ions situated in the periphery are occupied by four DMF and two water molecules. Magnetic studies on 1 reveal a frequency-dependent response which is characteristic of single-molecule magnets. © 2014 Elsevier Ltd. All rights reserved.

Polyhedron

Synthesis, structure and magnetism of the mixed-valent phosphonate cage, [MnIIMnIII12(μ4-O) 6(μ-OH)6(O3P-t-Bu)10(OH 2)2(DMF)4]·[2MeOH·4DMF]

Science of Advanced Materials

Ultra-Fast Synthesis of Graphene and Highly Oriented Graphite by Rapid Microwave Heating Process

Dalton Transactions

Heterometallic coordination polymers incorporating dipyrrin based heteroleptic copper and cobalt complexes: to Ag–π or not?

Luminescence and Electrochemical Properties of Organostannoxane Coordination Polymer Based on Ferrocenyl-2-Cyano Carboxylate Ligand

Journal	Asian Journal of Chemistry
Publisher	Asian Journal of Chemistry
ISSN	0970-7077
Open Access	No