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Mechanical Alloying of Metal–Organic Frameworks
, S. Horike, K. Hagi, N. Ogiwara, K. Kadota, T. Itakura, M. Tsujimoto, S. Kitagawa
Published in Wiley-VCH Verlag
2017
PMID: 28112472
Volume: 56
   
Issue: 9
Pages: 2413 - 2417
Abstract
The solvent-free mechanical milling process for two distinct metal–organic framework (MOF) crystals induced the formation of a solid solution, which is not feasible by conventional solution-based syntheses. X-ray and STEM-EDX studies revealed that performing mechanical milling under an Ar atmosphere promotes the high diffusivity of each metal ion in an amorphous solid matrix; the amorphous state turns into the porous crystalline structure by vapor exposure treatment to form a new phase of a MOF solid solution. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
About the journal
JournalData powered by TypesetAngewandte Chemie - International Edition
PublisherData powered by TypesetWiley-VCH Verlag
ISSN14337851