1-Glycyl-3-methyl imidazolium chloride-iron (III) complex [[Gmim]Cl-Fe(III)] was found to be a heterogeneous catalyst for an efficient and greener solvent free synthesis of esters by the condensation of carboxylic acids and alcohols with excellent yield at ambient temperature. This operation formulates very interesting, ecological perspective due to simple reaction condition, isolation, and purification of products. In addition, this method features reusability of catalyst, reduced waste, thus making new protocol more environmentally suitable whilst no catalyst leaching was observed. © Iranian Chemical Society 2012.

Karthikeyan P

Department of Computer Applications

School of Information Technology and Engineering

Vellore Campus

Senthilkumar S

Department of Chemistry

School of Advanced Sciences

Pundlik Rambhau Bhagat

Muskawar P.N

Aswar S.A.

Vellore Institute of Technology (VIT) is a private university located in&nbsp;Tamil Nadu, India. Founded in 1984, as Vellore Engineering College, the institution offers 20 undergraduate, 34 postgraduate, four integrated and four research programs. It has campuses in Vellore, Amravati, Bhopal and Chennai.

VIT is one of the top ranked private universities in India according to NIRF, THE and QS Rankings.&nbsp;Govt. of India has recognized&nbsp;VIT, Vellore as an&nbsp;Institution of Eminence. This has allowed VIT to take independent quality initiatives and move up in world ranking.

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VIT University

Journal of the Iranian Chemical Society

A mild, efficient, and eco-friendly procedure for the conversion of aliphatic, alicyclic and aromatic carbonyl compounds into the corresponding oximes, was catalyzed by a novel imidazolium based ionic liquid coupled with amino acid (asparagine) (L-AAIL, L-Amino acid functionalized ionic liquid) catalytic system. The quantitative conversion of aryl and alkyl carbonyl compounds into the corresponding oximes was achieved by simply grinding at ambient temperature using 0.05 mmol of catalyst in 50 s. In addition, this L-AAIL catalyst exhibited good reusability for five consecutive trials without significant loss of its catalytic activity. © 2011

Fulltext

Arabian Journal of Chemistry

A novel l-amino acid ionic liquid for quick and highly efficient synthesis of oxime derivatives – An environmental benign approach

A novel 1-glycyl-3-methyl imidazolium chloride-palladium (II) complex [[Gmim]Cl-Pd (II)] was found to be a heterogeneous catalyst for an efficient Heck reaction with good to excellent yield under solvent free condition. Tetra-coordinated palladium complex was prepared by reacting PdCl 2 with 1-glycyl-3-methyl imidazolium chloride and its catalytic function invented for the CC bond formation. Spectroscopic evidence of complex has been proved by powder XRD, SEM, FT-IR and AFM. This protocol provides a simple strategy for the generation of a variety of new CC bonds under environmentally benign condition. © 2012 Elsevier B.V. All rights reserved.

Journal of Molecular Catalysis A: Chemical

Development of an efficient solvent free one-pot Heck reaction catalyzed by novel palladium (II) complex-via green approach

Journal of Organometallic Chemistry

Synthesis of two-coordinate iron aryloxides and their reactions with organic azide: Intramolecular C–H bond amination

Chemical Engineering Journal

Tethering of Cu(II), Co(II) and Fe(III) tetrahydro-salen and salen complexes onto amino-functionalized SBA-15: Effects of salen ligand hydrogenation on catalytic performances for aerobic epoxidation of styrene

2011 Chinese Control and Decision Conference (CCDC)

Fault-tolerant control of nonlinear system

Novel and efficient method for esterification catalyzed by 1-glycyl-3-methyl imidazolium chloride-iron (III) complex

Journal	Data powered by TypesetJournal of the Iranian Chemical Society
Publisher	Data powered by TypesetSpringer Science and Business Media LLC
ISSN	1735-207X
Open Access	0