Header menu link for other important links
X
On the giant magnetocaloric and mechanical properties of Mn–Fe–P–Si-Ge alloy
Kanikrishnan Sethupathi, Raghavan Gopalan, Kavita S, , Bhatt P, Suresh V, , Sethupathi K, Gopalan R.
Published in Elsevier Ltd
2020
Volume: 817
   
Abstract
We report the magnetocaloric properties of Mn1.15Fe0.85P0.65Si0.13Ge0.2B0.02 alloy prepared by mechanical alloying followed by spark plasma sintering and annealing the spark plasma sintered alloy. The X-ray diffraction pattern confirms the presence of hexagonal Fe2P-type phase in both (as-prepared and annealed) alloys. Annealing of the spark plasma sintered alloy leads to the increase of the volume fraction of the Fe2P phase from 87% to 98% and a decrease in the lattice volume. Thermo-magnetic measurements show that Curie temperature (TC) decreases from 291 K to 289 K after annealing the spark plasma sintered alloy. Thermal hysteresis reduces from 19 K to 9 K after annealing the spark plasma sintered alloy. The magnetic entropy evaluated from magnetization measurements was found to be 8 J/kg-K in the spark plasma sintered alloy and it increases to 19 J/kg-K in the annealed spark plasma sintered alloy under 3 T magnetic field. The refrigerant capacity of the annealed spark plasma sintered alloy was found to be 200 J/kg at 3 T. The adiabatic temperature change of the annealed alloy has been estimated from the heat capacity measurements and it was found to be 1.9 K at 1 T and increases to around 2.7 K under a magnetic field of 3 T. Annealing the spark plasma sintered alloy leads to decrease in the hardness and it is observed that both the alloys crack after thermal cycling. However, the large change in magnetic entropy and adiabatic temperature change very near to the room temperature makes Mn1.15Fe0.85P0.65Si0.13Ge0.2B0.02 alloy a promising magnetocaloric material. © 2019 Elsevier B.V.
About the journal
JournalData powered by TypesetJournal of Alloys and Compounds
PublisherData powered by TypesetElsevier Ltd
ISSN09258388
Open AccessNo
Concepts (20)
  •  related image
    Annealing
  •  related image
    Entropy
  •  related image
    Magnetic fields
  •  related image
    Magnetoplasma
  •  related image
    Manganese alloys
  •  related image
    Mechanical alloying
  •  related image
    Mechanical properties
  •  related image
    Si-ge alloys
  •  related image
    Spark plasma sintering
  •  related image
    Specific heat
  •  related image
    Thermal conductivity
  •  related image
    Adiabatic temperature change
  •  related image
    Heat capacity measurements
  •  related image
    Magnetic entropy
  •  related image
    Magnetization measurements
  •  related image
    Magnetocaloric materials
  •  related image
    Magnetocaloric properties
  •  related image
    Refrigerant capacity
  •  related image
    Thermal hysteresis
  •  related image
    Iron alloys