Naturally derived nanocellulose (NC) is a renewable, biodegradable nanomaterial with high strength, low density, high surface area, and tunable surface chemistry, which allows its interaction with other polymers and nanomaterials in a controlled manner. In recent years, NC aerogel has gathered a lot of attention due to environmental concerns. This review presents recent developments of NC-based aerogels and their controlled interactions with other polymers and nanomaterials for thermal applications that include electronic devices, the apparel industry, superinsulating materials, and flame-retardant smart building materials. After going through the distinctive properties of NC aerogels, they are orderly categorized and discussed as thermally insulated, thermally conductive, and flame-retardant materials. ©