In this paper, we introduce the various types of generalized invexities, i.e., α f -invex/ α f -pseudoinvex and ( G , α f ) -bonvex/ ( G , α f ) -pseudobonvex functions. Furthermore, we construct nontrivial numerical examples of ( G , α f ) -bonvexity/ ( G , α f ) -pseudobonvexity, which is neither α f -bonvex/ α f -pseudobonvex nor α f -invex/ α f -pseudoinvex with the same η . Further, we formulate a pair of second-order non-differentiable symmetric dual models and prove the duality relations under α f -invex/ α f -pseudoinvex and ( G , α f ) -bonvex/ ( G , α f ) -pseudobonvex assumptions. Finally, we construct a nontrivial numerical example justifying the weak duality result presented in the paper.