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Structural and mechanical properties of low dielectric constant SiOC(-H) films using MTES/O2 deposited by PECVD
, A. Zakirov, H.S. Kim, Y.J. Jang, A.S. Jung, C.K. Choi
Published in Trans Tech Publications Ltd
2007
Volume: 124-126
   
Issue: PART 1
Pages: 239 - 242
Abstract
Low dielectric constant SiOC(-H) films were deposited on p-type Si (100) substrates by plasma enhanced chemical vapor deposition (PECVD) using methyltriethoxysilane (MTES; C7H18O3Si) and oxygen gas as precursors. The SiOC(-H) films were deposited at room temperature and then annealed. Nanoindentation studies were carried out in order to determine the mechanical properties of the SiOC(-H) films. The elastic modulus and hardness of SiOC(-H) films were measured to be in the range of 2.14 - 5.02 and 0.12 - 0.74 GPa, respectively. It was observed that the values of elastic modulus and hardness decreases with increase of flow rate ratio of the precursors. In the SiOC(-H) film, -CH3 group as an end group was introduced into -O-Si-O- chain network, thereby reducing the film density to decrease the values of the mechanical properties.
About the journal
JournalSolid State Phenomena
PublisherTrans Tech Publications Ltd
ISSN10120394