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Structural, optical, dielectric, second and third-order nonlinear properties of new semiorganic crystal: Sodium (bis) boro succinate
Rajasekar G, Dhatchaiyini M.K, , Bhaskaran A.
Published in Elsevier BV
Volume: 1177
Pages: 594 - 602
A new semiorganic nonlinear optical crystal Sodium (bis) boro succinate (SBBS) [Na2 (C4H4O4) (H3BO3)(H2O)4]·H3BO3 was grown from aqueous solution by slow evaporation growth technique. Single crystal X-ray diffraction analysis revealed that the crystal belongs to monoclinic crystal system with space group of P21/n. The crystalline nature of SBBS crystal was analyzed by Powder X-ray diffraction. The morphology and growth axis of grown crystal were investigated. The functional groups present in the compound were confirmed by FTIR and FT-Raman spectroscopy techniques. The cut-off wavelength, optical transmission and band gap energy of the grown crystal were analysed by UV–Visible spectral studies. Electrical behaviour of SBBS crystal was analysed by dielectric studies. Laser induced damage threshold study was carried out for SBBS crystal using Nd:YAG laser. Second harmonic generation and relation between particle sizes with respect to generated output were investigated by Kurtz-Perry powder technique. Third order nonlinear properties of SBBS crystal were analyzed by Z-scan method and the corresponding nonlinear refractive index, absorption coefficient and optical susceptibility were calculated. © 2018
About the journal
JournalData powered by TypesetJournal of Molecular Structure
PublisherData powered by TypesetElsevier BV
Open AccessNo