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Synthesis and characterization of the first metallacyclooctane
, H. Su, J.R. Moss
Published in
2008
   
Issue: 17
Pages: 2228 - 2231
Abstract
Ring closing metathesis (RCM) using Grubbs’ 1st generation catalyst with cis-[L2Pt(CH2CH2CH═CH2)(CH2CH2CH2CH═CH2)] yields a platinacyclooctene which can be hydrogenated to the platinacyclooctane, L2Pt(CH2)7 [L2 = Ph2PCH2CH2CH2PPh2 (dppp) or Ph2PCH2CH2PPh2 (dppe)] in high yield. © 2008 The Royal Society of Chemistry.
About the journal
JournalJournal of the Chemical Society. Dalton Transactions
ISSN14779226