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The local hypernetted-chain approximation for the 2:1 restricted primitive model electrolyte at a charged hard wall
P. Nielaba, T. Alts, , F. Forstmann
Published in
1986
Volume: 34
   
Issue: 2
Pages: 1505 - 1511
Abstract
A local HNC/HNC and a HNC/HNC (hypernetted-chain) treatment of the double layer for 2:1 electrolytes is presented. The local HNC/HNC treatment produces improved structure information about the double layer. For divalent counter-ions, nonmonotonic co-ion profiles and improved charge inversions near the electrode are obtained as well as improved diffuse layer potentials; for monovalent counter-ions, packing layers build up at high surface charges. These are effects due to the treatment of the ionic correlations in non-neutral homogeneous systems with the local composition of the electrolyte in front of the electrode. At zero surface charge, a nonzero surface potential is obtained. © 1986 The American Physical Society.
About the journal
JournalPhysical Review A
ISSN10502947