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Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: Synthesis and applications
, S. Drucker, N. Fridman, M.S. Eisen
Published in Royal Society of Chemistry
PMID: 28678261
Volume: 46
Issue: 36
Pages: 12005 - 12009
Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism. © 2017 The Royal Society of Chemistry.
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JournalData powered by TypesetDalton Transactions
PublisherData powered by TypesetRoyal Society of Chemistry