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Ultrasonic-Assisted Hypervalent Iodine-Catalyzed Cyclization of (E)-2-Hydroxystilbenes to Benzofurans Using Iodobenzene as Pre-catalyst
S.R. Mangaonkar, S.E. Shetgaonkar, A.A. Vernekar,
Published in Wiley-Blackwell
2020
Volume: 5
   
Issue: 34
Pages: 10754 - 10758
Abstract
A rapid, and metal-free approach for the synthesis of functionalized benzofurans 10 is illustrated by PhI 9 catalyzed cyclization of 2-hydroxystilbenes 8. The 2-hydroxystilbenes 8 were cyclized using 10 mol % PhI as a precatalyst, 2.0 equiv. of m-CPBA as an oxidant and 2.4 equiv. of TFA as an additive at room temperature under ultrasonic irradiation condition. The functionalized benzofurans 10 were gained in good to excellent yields with shorter reaction times. © 2020 Wiley-VCH GmbH
About the journal
JournalData powered by TypesetChemistrySelect
PublisherData powered by TypesetWiley-Blackwell
ISSN23656549