Organic material of bis(cyclohexylammonium) succinate succinic acid (BCSSA) single crystal was grown by slow evaporation technique at room temperature and bulk of BCSSA was grown by slow cooling method. Single crystal XRD analysis reveals that the BCSSA crystal belongs to the triclinic crystal system with centro-symmetric space group (P1¯) The FT-IR spectrum confirm the functional groups of NH3+, succinate and succinic acid present in the BCSSA crystal, showing the evidence of compound formation and optical band gap was calculated using UV-Vis-NIR analysis. The third order nonlinear optical parameters were calculated by Z scan technique using 532 nm diode pumped CW Nd:YAG Laser and the optical limiting spectrum of BCSSA shows the suitability in optical limiting applications. © 2017 Elsevier B.V.

Gomathi S

Department of General Management

VIT Business School

Vellore Campus

Madeswaran S

Department of Physics

School of Advanced Sciences

Babu D.R.

Fulltext

Vellore Institute of Technology (VIT) is a private university located in&nbsp;Tamil Nadu, India. Founded in 1984, as Vellore Engineering College, the institution offers 20 undergraduate, 34 postgraduate, four integrated and four research programs. It has campuses in Vellore, Amravati, Bhopal and Chennai.

VIT is one of the top ranked private universities in India according to NIRF, THE and QS Rankings.&nbsp;Govt. of India has recognized&nbsp;VIT, Vellore as an&nbsp;Institution of Eminence. This has allowed VIT to take independent quality initiatives and move up in world ranking.

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VIT University

Materials Chemistry and Physics

Paracetamol-Picric acid (PP) cocrystals were grown from ethanol by slow evaporation solution growth technique. The compound C14H12N4O9 crystallizes in monoclinic system with centrosymmetric space group P21/c. The band gap energy was estimated by the application of Kubelka–Munk algorithm and the cut-off wavelength is ∼491 nm. The molecule is associated with accommodating weak C[sbnd]H⋯O, O[sbnd]H⋯O, π … π and H⋯H stacking interactions, very much responsible for the formation and strengthening of supramolecular assembly. Inter- and intramolecular hydrogen bonding interactions show supramolecular architecture in the crystal packing. Third-order nonlinear optical properties of the grown crystal were derived by employing a single beam Z-scan technique at a wavelength of 532 nm diode pumped CW Nd:YAG Laser system. Theoretical calculations were performed using density functional theory (DFT) method to derive the optimized geometry, dipole moment, polarizability and hyperpolarizability. Molecular interactions are analyzed and quantified by Hirshfeld surfaces, derived from single crystal XRD data. Fingerprint plots of Hirshfeld surfaces were used to locate and analyze the percentage of hydrogen bonding interactions. The O⋯H/H⋯O interactions mainly contribute to the observed microlevel nonlinearity. © 2019

Journal of Molecular Structure

Cocrystallization of Paracetamol-Picric acid: Hirshfeld surface analysis, supramolecular architecture and third-order nonlinear optical properties

Organic bulk single crystal of cyclohexylaminium hydrogen phthalate hemihydrate (CYHPH) was grown by slow cooling method using methanol as a solvent. The grown crystal belongs to orthorhombic system with Pbcn space group and it has various functional groups such as NH3 +, phthalate and a water molecule. The cut off wavelength of CYHPH was found at 307 nm. Thermal analysis affirmed that the CYHPH compound was stable up to 146 °C and completely decomposed at 263 °C. The activation energy at 100 Hz, 1 and 10 KHz was found to be 0.31, 0.141 and 0.142 eV respectively. The grown CYHPH crystal exhibits third order nonlinear optical behavior. © 2017, Springer Science+Business Media New York.

Journal of Materials Science: Materials in Electronics

Growth and characterization of cyclohexylaminium hydrogen phthalate hemihydrate nonlinear optical single crystals

Corrigendum to “Bulk monocrystal growth, optical, dielectric, third order nonlinear, thermal and mechanical studies on HCl added l-alanine: An organic NLO material” [Mater. Chem. Phys. 184 (2016) 12–22]

Journal of Crystal Growth

Studies on the growth aspects, structural and third-order nonlinear optical properties of Piperidinium 3-carboxy-4-hydroxy benzenesulfonate single crystal

Experimental and theoretical investigation on 2-amino 5-bromopyridinium L-tartrate-A new organic charge-transfer crystal for optoelectronics device applications

Growth and characterization of 2-methylquinolinium L-malate single crystal

Bulk growth, electrical, linear, third order nonlinear optical and optical limiting properties on bis(cyclohexylammonium) succinate succinic acid crystal

Journal	Data powered by TypesetMaterials Chemistry and Physics
Publisher	Data powered by TypesetElsevier BV
ISSN	0254-0584
Open Access	No