Zirconium Dioxide (ZrO2) Thermal Barrier Coatings (TBCs) were produced on nickel based superalloys (Inconel-625) by plasma spray coatings. Hot corrosion behaviour of the ZrO2 TBCs was investigated in presence of K2SO4–40%NaCl at 800 °C in air oxidation and molten salt environment under cyclic conditions for 50 cycles. The thermo-gravimetric technique was used to establish the kinetics of corrosion. The corrosion products have been analysed using the SEM and EDS analysis. Results show that the ZrO2 coating exhibits superior stability in air oxidation to molten salt environment against hot corrosion. © 2014, Sphinx Knowledge House. All rights reserved.