A simple redox transformation between a vanadium(iii) metal complex and gold(iii) chloride aided by a cost-effective modified hydrothermal procedure has been adopted for the synthesis of Au-V2O5 composite nanowires. The stability of pseudocapacitive electrode materials in acidic electrolytes is a major challenge. However, the synthesized Au-V2O5 composite nanowires are stable in acidic electrolyte when compared to the precursor component, V2O5. Electrochemical measurement shows a specific capacitance of 419 F g-1 at 1 A g-1 current density in 0.5 M H2SO4 solution for the synthesized composite nanowires. However, the precursor component V2O5 shows a lower specific capacitance under identical conditions. The synthesized composite nanowires, as a pseudocapacitive electrode material, respond to a wide range of working potential windows (+1.6 V), resulting in maximum energy and power densities of 53.33 W h kg-1 and 3.85 kW kg-1 respectively. Moreover, the Au-V2O5 nanowires show high cyclic stability (89% specific capacitance retention) for up to 5000 consecutive charge-discharge (CD) cycles at 10 A g-1 constant current density, due to the composite formation by redox transformation, which reflects the stability of the composite in acidic electrolyte. © the Partner Organisations 2018.