This paper, we studied the magnetohydrodynamic chemically reacting unsteady flow over a radiated sheet with partial slip and variable conductivity. The arising set of governing equations are transformed by utilizing self- similarity changes and unraveled by utilizing numerically R-K (Runge-Kutta) with shooting technique. The analysis further explains that the non-dimensional parameters on temperature, concentration and velocity fields along with rate of mass and heat transfer and friction factor are and present in graphically and computed in tabular form. The numerical simulation carried out in two cases (with suction and without suction case). Rises in porosity parameter enhances then reduce rate of heat transfer (Nusselt number) and mass transfer (Sherwood number) as well as friction factor coefficient (skin friction). © 2020 Author(s).