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Anodic TiO2 from stirred Na2SO4/NaF electrolytes: Effect of applied voltage and stirring
, T.-Y. Kwon, K.-H. Kim
Published in
2009
Volume: 63
   
Issue: 23
Pages: 2003 - 2006
Abstract
TiO2 was anodically formed on titanium from electrolyte containing 1M Na2SO4 and 0.5 wt.% NaF. Oxidation was carried out for 1 h at potentiostatic 20, 30 and 40 V from unstirred as well as stirred baths. At 20 V amorphous and nanotubular oxide is produced irrespective of the stirring conditions. Stirring increased the tubular length compared to the unstirred condition at 20 V. Oxidations at 30 and 40 V produced flat, crystalline anatase under both the bath conditions. A nanotubular network may be formed in the first 5 min and then anodic oxidation may occur laterally, perpendicular to the long-axis of the nanotubes. © 2009 Elsevier B.V. All rights reserved.
About the journal
JournalMaterials Letters
ISSN0167577X