Urea-SCR has received worldwide attention for reducing the harmful NOx emission from present diesel engines. But this faces lot of challenges such as complete decomposition of reducing agent urea and its deposition at the bottom of exhaust tail pipe, lack of uniform distribution of the urea-decomposed ammonia during the continuous running of the engine. This study is involved with CFD evaluation of urea decomposition rate by adopting different urea injection angles and nozzle positions. Also, urea atomization and evaporation/decomposition to ammonia and ammonia distribution on tail pipe cross-sectional area are investigated. Exhaust tail pipe is fitted with guided pipe at different angles. Also, urea and air are injected at different pressures respectively, in the twin-flow nozzle. The CFD analysis indicated that, the ammonia conversion rate is well improved using guided pipe fitted at 30° inclination with exhaust tail pipe. The CFD analysis is validated by engine experiments. It was proven that, the conversion increased for the 5bar urea and 1bar air. © RASĀYAN. All rights reserved.