Vellore Institute of Technology (VIT) is a private university located in&nbsp;Tamil Nadu, India. Founded in 1984, as Vellore Engineering College, the institution offers 20 undergraduate, 34 postgraduate, four integrated and four research programs. It has campuses in Vellore, Amravati, Bhopal and Chennai.

VIT is one of the top ranked private universities in India according to NIRF, THE and QS Rankings.&nbsp;Govt. of India has recognized&nbsp;VIT, Vellore as an&nbsp;Institution of Eminence. This has allowed VIT to take independent quality initiatives and move up in world ranking.

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VIT University

VIT Unitversity

Centre for Nanotechnology Research

Vellore Campus

Department of Communication Engineering

School of Electronics Engineering

Journal of Computational Electronics

Negative VCC in MIM capacitors: modeling and experiments

We report a simple PEG-600 assisted solvothermal method for the synthesis iron ferrite with functionalized multi-walled carbon nanotube (Fe3O4/fMWCNT) composite nanoassemblies. The results show that the composite deliver excellent electrochemical activity because of the synergistic effect of each component. The fMWCNT act as a conductive network with high surface area promoting fast movement of electrons which enhances the charge storing nature and stability of Fe3O4 nanoassemblies. © 2018 Author(s).

AIP Conference Proceedings

Enhanced supercapacitive behaviour of Fe3O4/fMWCNT nanoassemblies synthesized by PEG-600 assisted solvothermal method

A new and facile approach is presented for generating quasi-regular patterns of transition metal-based nanoparticles on flat substrates exploiting polystyrene-block-poly2vinyl pyridine (PS-b-P2VP) micelles as intermediate templates. Direct loading of such micellar nanoreactors by polar transition metal salts in solution usually results in nanoparticle ensembles exhibiting only short range order accompanied by broad distributions of particle size and inter-particle distance. Here, we demonstrate that the use of P2VP homopolymers of appropriate length as molecular carriers to transport precursor salts into the micellar cores can significantly increase the degree of lateral order within the final nanoparticle arrays combined with a decrease in spreading in particle size. Thus, a significantly extended range of materials is now available which can be exploited to study fundamental properties at the transition from clusters to solids by means of well-organized, well-separated, size-selected metal and metal oxide nanostructures. © 2013 The Royal Society of Chemistry.

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Fulltext

Journal of Materials Chemistry C

Homopolymers as nanocarriers for the loading of block copolymer micelles with metal salts: A facile way to large-scale ordered arrays of transition-metal nanoparticles

A rapid and facile route allows the self-assembly of precursor micelles loaded with metal salts on an unprecedented short timescale. Micellar arrays can then be transformed into high-quality (metal or metal oxide) nanoparticle arrays. This promising route offers functionalization of surfaces by nanomaterials on industrially relevant timescales. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Angewandte Chemie - International Edition

Ultrafast self-assembly using ultrasound: A facile route to the rapid fabrication of well-ordered dense arrays of inorganic nanostructures

We demonstrate a simple and effective approach to control the diameter of ultrathin ZnO nanowires with high aspect ratios and high densities over large areas. Diblock copolymer-based nanoparticle arrays exhibiting a high degree of hexagonal order and offering easy control of particle size (typically 1–10 nm) and interparticle spacing (25–150 nm) are utilized as nanocatalysts for the subsequent growth of semiconductor nanowires. The as-grown ZnO nanowires exhibit a single crystal hexagonal wurtzite structure and grow along the [0002] direction. Facetted catalyst particles were observed at the tip of the nanowires after synthesis, thus suggesting a catalyst-assisted vapor–solid–solid (VSS) rather than a vapor–liquid–solid (VLS) growth mechanism, the latter being frequently used in semiconductor nanowire production. Such a growth process allows us to easily prepare ultrathin ZnO nanowires with tunable diameters well below 10 nm by taking advantage of the inherent size control of the micellar method during deposition of the catalyst nanoparticles. Raman spectroscopy reveals a phonon confinement effect as the diameter of nanowires decreases. Photoluminescence spectra of these ultrathin nanowires indicate a blue shift of the free excitons and their phonon replicas by 37 meV induced by quantum confinement. © 2013 The Royal Society of Chemistry.

Nanoscale

Controlled synthesis of ultrathin ZnO nanowires using micellar gold nanoparticles as catalyst templates

In this article, we describe a novel straightforward method for the specific identification of viable cells (macrophages and cancer cell lines MCF-7 and Jurkat) in a buffer solution. The detection of the various cell types is based on changes of the heat transfer resistance at the solid-liquid interface of a thermal sensor device induced by binding of the cells to a surface-imprinted polymer layer covering an aluminum chip. We observed that the binding of cells to the polymer layer results in a measurable increase of heat transfer resistance, meaning that the cells act as a thermally insulating layer. The detection limit was found to be on the order of 104 cells/mL, and mutual cross-selectivity effects between the cells and different types of imprints were carefully characterized. Finally, a rinsing method was applied, allowing for the specific detection of cancer cells with their respective imprints while the cross-selectivity toward peripheral blood mononuclear cells was negligible. The concept of the sensor platform is fast and low-cost while allowing also for repetitive measurements. © 2013 American Chemical Society.